A solution containing methoxide ions, CH30* ions, in methanol can be prepared by adding sodium hydride to methanol: Organic Chemistry Assignment, UPM, Malaysia

University Universiti Putra Malaysia (UPM)
Subject Organic Chemistry
  • a) A solution containing methoxide ions, CH30* ions, in methanol can be prepared by adding sodium hydride to methanol. Flammable gas is the other product. Write the acid-base reaction that takes place.
    b) Write the nucleophilic substitution that takes place when Chii is added the resulting solution is heated.
  • Write the following as net ionic equations and designate the nucleophile, substrate, and leaving the group in each case.

  • Heating optically active -3-Bromo-3-methyl hexane with aqueous acetone results in the formation of 3-methyl-3-hexanol as a mixture of 50 % and 50 %. Write the (stereochemistry) mechanism of the SN 1 reaction.
  • Treating tert-butyl chloride with 80 % aqueous ethanol at 25 °C gives substitution products in 83 % yield and elimination products in 17 % yield. Write the mechanism for the El reaction.

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